WK-CeraCAT
Ceramic All-in-one Integrated Gas Treatment Technology
for denitration, desulfurization, dust removal, dioxin elimination etc.
The WK-CeraCAT ceramic catalytic filter tube ultra-low emission integrated system for pollutants is a ceramic ceramic integrated industrial kiln flue gas ultra-low purification system that integrates denitrification, desulfurization, defluorination, dust removal, alkali and heavy metal removal through the core element multi tube bundle system. The successful application of this technology not only solves the technical problem of high concentration NOx, high concentration SO2, H2S, HF and other acidic components in industrial kiln flue gas that are difficult to achieve ultra-low emissions, but also overcomes technical bottlenecks such as catalyst poisoning and activity reduction caused by high alkali and heavy metal content in smoke, and effectively solves the conditioning of viscous flue gas conditions, ensuring the long-term stable operation of the integrated system.
Features
Based on the independently developed WK CeraCAT ceramic catalytic filter technology, the company has launched a globally leading ceramic integrated flue gas treatment system, which achieves collaborative treatment of multiple pollutants such as desulfurization, denitrification, defluorination, and dust removal, achieving ultra-low emissions. Combined with artificial intelligence algorithms, it accurately denitrifies and effectively controls ammonia escape. The core component of this technology is the ceramic catalytic filter tube, which is made of ceramic fiber as the basic material and formed through centrifugal fabric technology. The ceramic tube body is deeply impregnated with SCR catalyst using nano impregnation technology, forming a ceramic catalytic filter element with efficient dust removal, desulfurization, and denitrification.
Integrated design
A single section can simultaneously complete desulfurization, denitrification, dust removal, and removal of pollutants such as dioxins, reducing the footprint by more than 50%.
Ultra Low Emission
Achieve over 99% removal efficiency of various pollutants, with the highest achievable near zero ultra-low emissions.
Low Cost
Combined with high-strength and low resistance ceramic filter tubes, it is more energy-efficient than traditional processes and also saves the use of environmentally friendly consumables. The core components of catalytic filter tubes have a longer service life than traditional SCR catalysts, with a maximum service life of over 8 years. The operating cost of ceramic integrated systems is equivalent to 60-70% of the operating cost of traditional processes.
Process Flow
The system consists of an adsorbent powder spraying unit, a reducing agent ammonia spraying unit, a conditioning tower unit, a ceramic catalyst filter tube reaction kettle unit, a waste ash treatment unit, a flue system, a control unit, and auxiliary units. Through the synergistic effect of multiple units, NOx, SO ₂ HF、 Efficient collaborative treatment of multiple pollutants such as dust, and strict control of ammonia escape, with advantages such as simple process, easy maintenance and operation, low operating costs, and long service life. Suitable for high pollutant treatment in industries such as glass kilns, coking, boilers, and waste incineration.
1. Pre treatment stage: flue gas conditioning and pollutant pre removal
- Conditioning tower unit: Through an efficient flue gas dry conditioning device, acidic substances such as SO2and viscous substances in the flue gas are pre removed, and a specially developed and produced static mixer is used to achieve uniform mixing of flue gas and lime powder, optimizing the flue gas conditioning effect and ensuring efficient removal of acidic pollutants in the flue gas..
- Adsorbent powder spraying unit: Based on the parameters of the user's kiln flue gas, it is recommended to use Ca (OH)2with a mesh size of not less than 300, purity>90%, and moisture<0.8% as the desulfurizer for dry flue gas desulfurization.. In order to efficiently utilize adsorbents, "Zhongtianweier" not only uses high-precision metering injection of adsorbents, but also adopts the company's independently developed anti clogging device design to ensure smooth powder feeding and non clogging. In the flue gas transportation process, it adopts a unique WK-TZ high-efficiency conditioning tower or WK-JT static mixer design in key parts of the flue gas duct, which not only effectively achieves uniform mixing of gas-solid two-phase flow, but also effectively improves the removal rate of acidic components in flue gas and reduces the amount of adsorbent used, as well as effectively controls the operating cost of adsorbents.
- Static mixing unit: After the flue gas is fully mixed with the adsorbent, it enters the static mixer and is uniformly mixed with the ammonia gas (NH3) accurately injected by thereducing agent ammonia injection unit..
2. Collaborative treatment of pollutants: integrated collaborative desulfurization, denitrification, and dust removal
- Reducing agent ammonia spraying unit: Generally, 20% ammonia water is used as the reducing agent. The ammonia spraying unit mainly consists of an efficient ammonia water atomization device, a spray gun distributor, a flue gas homogenization device, and a self-control unit. It is an important part of fully atomizing ammonia water and mixing it evenly with flue gas, directly affecting the subsequent denitrification reaction effect. The ammonia spray high-efficiency atomization device independently developed and designed by "Zhongtianweier" has unique technical advantages and can achieve maximum flue gas denitrification effect.
- Ceramic catalyst filter tube reaction kettle device(Core link): The design of Zhongtianweier reaction kettle is completely based on the German design concept of ceramic integration, incorporating the differences and flue gas characteristics of domestic glass kilns. From the inlet flue of the reaction kettle to each independent chamber, smooth simulation analysis of flue gas flow is carried out. Not only is the flue guide plate embedded, but also the chamber guide plate design is embedded to ensure that the flue gas enters the reaction kettle with uniform and smooth distribution, ensuring the high efficiency of the ceramic catalyst tube multi bundle and the system, effectively reducing the consumption of consumables, preventing ammonia escape, etc.
3. Waste ash treatment unit
- Backblowing and dust cleaning: Based on the problem of high calcium sulfur ratio in traditional ceramic integrated system calcium hydroxide dry desulfurization, Zhongtianweier uses intelligent algorithms and high-efficiency energy-saving control methods to optimize the blowback parameters, effectively improving the utilization rate of calcium hydroxide powder.
- Dust collection and pneumatic conveying device: Concentrate dust collection at the discharge port of the integrated ceramic desulfurization, denitrification, and dust removal equipment, and transport it to the waste bin to ensure a clean on-site environment and avoid personal injury to on-site operators; During the dust collection control process, based on the high limit alarm signal of each reaction kettle ash hopper, the system starts the unloader and unloads the ash according to the order of the alarm signal. The time for each unloading cycle can be set in the reserved window on the interface.
4. Flue unit
- The process pipeline unit in the front section of the tempering tower mainly includes the powder spraying process pipeline and the tempering Venturi pipeline. The process pipeline must ensure the flow rate of flue gas to prevent pipeline blockage caused by adsorbent settling. The design of the flue should minimize the pressure drop of the system and optimize the layout, shape, and internal components (such as guide plates and turning guide plates).
5. Control unit
The control system adopts DCS control system, which is responsible for processing signals detected by various detection probes and commanding the operation of the entire system according to established rules.
- Monitoring section - mainly displays online monitoring (CEMS) and instrument and instrument signal feedback, using centralized control by the upper computer.
- Control system - mainly composed of power cabinet, DCS system control cabinet, frequency conversion control cabinet, on-site equipment control cabinet, on-site electrical equipment, etc.
Reaction mechanism
Ceramic catalyst tube filters can be implemented in a single device to simultaneously remove sulfur oxides, nitrogen oxides, hydrogen chloride, hydrogen fluoride, dust, and dioxins.
- Remove dust from flue gas through the surface of a tubular filter.
- Use lime or bicarbonate to remove SOx by pre coating on the catalyst tube filter.
- SO2 + Ca(OH)2 = CaSO3 + H2O
- CaSO3 + ½ O2 = CaSO4
- SO3 + Ca(OH)2 = CaSO4 + H2O
- 2HCl + Ca(OH)2 = CaCl2 + 2H2O
- 2HF + Ca(OH)2 = CaF2 + 2H2O
- When using NH3 or urea as a reducing agent to achieve denitrification through a 20mm catalytic layer, the flue gas undergoes denitrification reaction with high removal rate and low NH3 escape efficiency.
- 4NO + 4NH3 + O2 = 4N2 + 6H2O
- 2NO2 + 4NH3 + O2 = 3N2 + 6H2O
- The entire process of decomposing dioxin compounds can be completed in one step in the reaction vessel without the need for reactants, solid waste disposal, or subsequent treatment.
Features of ceramic integrated system
Efficient Dust Removal
Suitable for efficient dust removal in various temperature ranges of 200-1000 degrees, with a maximum dust removal efficiency of up to 99%. It can completely replace electrostatic precipitator and bag filter technology.
Efficient NOx Removal
Solved the problems of catalyst blockage and poisoning caused by smoke and dust in SCR/SNCR, greatly improving the efficiency of denitrification and the service life of the catalyst.
Efficient SOx Removal
Solved the problems of low efficiency of traditional dry desulfurization and other acidic components, high solid waste, secondary pollution of wet desulfurization wastewater, and white smoke emissions.
High system reliability
The new process enables multi chamber design and non-stop maintenance, enabling online catalyst activation and single chamber isolated catalyst regeneration control mode.
Industry Applications
Removal rate of over 99% for various pollutants
Compared with traditional craftsmanship, ceramic integrated technology reduces the proportion of area by at least 50%
Compared with traditional craftsmanship, it can reduce operation and maintenance costs by 60% -70%
We have helped over 50 companies reduce costs, increase efficiency, save energy, and reduce emissions
Process Comparison
Comparison of Ceramic Integration Solutions with Traditional Craftsmanship
Traditional medium temperature SCR flue gas purification process | Ceramic integrated flue gas purification process | |
---|---|---|
Process Flow | Kiln flue gas+electrostatic precipitator+medium temperature SCR denitration+desulfurization tower+bag filter | Kiln flue gas+dry conditioning+ceramic catalyst sulfur and nitrate dust integrated reaction kettle |
Purification target | Desulfurization, denitrification, and dust removal | Desulfurization, denitrification, defluorination, dehydrochlorination, dioxin removal, dust removal |
Denitrification efficiency | ≤85% | ≥95% |
Dust removal efficiency | Medium-High,≥20mg/Nm³ | High,≤5mg/Nm³(Typical:2mg/Nm³) |
Improvement space for indicators | Unable to adapt to future national standards | Can be upgraded to ultra-low emissions |
operational stability | The system process is complex and the stability is poor | The system has a simple process and high reliability |
Catalyst lifespan | 2-3 years (domestic catalysts require frequent activation) | Foreign cases with over 8 years of experience |
Pressure drop | High | Low, ≤ 2500Pa (typical value: 1500Pa) |
Operating costs | High | Low (60-70% of traditional craftsmanship) |
Investment Cost | Medium | A bit high |
Reaction temperature zone | 350-420℃ | ≥200℃ |
Floor Area | Big | Small |